major contributor to the halving of the battery’s capacity mentioned
As HP Compaq Business Notebook NX6300 Series Battery go, the rechargeable lithium-ion variety is among the greenest options available. They can last for years, they are recyclable, and they don’t contain the toxic heavy metals found in many of their Walkman-powering predecessors.
At this point, the authors calculate, the primary limiting factor is no longer storing lithium in the Toshiba Satellite M200 Battery ; instead, getting the lithium in contact with an electrode is what slows things down. The electrodes also become a problem because they need to occupy more of the volume of the Laptop Batteries in order to maintain this rate of charge, which lowers the charge density. That’s a major contributor to the halving of the battery’s capacity mentioned in the previous paragraph.
Ross Dueber, the company’s chief executive, says a top-tier laptop manufacturer will release the first computer designed to accept silver-zinc batteries in mid-2009. The laptop’s runtime with silver-zinc will increase from the roughly 5 hours afforded by a typical lithium-ion battery to at least 7 hours, according to Mr. Dueber.
The results are pretty astonishing. At low discharge rates, a cell prepared from this material discharges completely to its theoretical limit (~166mAh/g). As the authors put it, “Capacity retention of the material is superior.” Running it through 50 charge/discharge cycles revealed no significant change in the total capacity of the HP Compaq Business Notebook NX6310 Battery.
In terms of the environment, ZPower has been touting its silver-zinc Toshiba Satellite M100 Battery as 95 percent recyclable by weight and containing no heavy metals or toxic chemicals. Still, silver is regulated as hazardous waste by the Environmental Protection Agency and can be harmful to aquatic life. So ZPower’s claim to greenness may depend largely on whether it can successfully entice customers to recycle.
A more significant problem is that these batteries may wind up facing an electric grid that was never meant to deal with them. A 1Wh cell phone battery could charge in 10 seconds, but would pull a hefty 360W in the process. A battery that’s sufficient to run an electric vehicle could be fully charged in five minutes—which would make electric vehicles incredibly practical—but doing so would pull 180kW, which is most certainly not practical.
ZPower says its batteries don’t explode. (Image: ZPower)“If ZPower follows through and does the materials recycling, that would be a significant improvement, because that’s not currently what happens if you recycle a lithium-ion battery in the United States,” Mr. Harrell said.
In the race to make the lithium-ion batteries that will run the electric cars of the future, the United States is losing to Asian countries, and start-ups and big companies need to band together to build a lithium-ion battery industry in the United States, says Jim Greenberger.